Improving metallic lithium anode with NaPF6 additive in LiPF6-carbonate electrolyte
نویسندگان
چکیده
منابع مشابه
A Review of Solid Electrolyte Interphases on Lithium Metal Anode
Lithium metal batteries (LMBs) are among the most promising candidates of high-energy-density devices for advanced energy storage. However, the growth of dendrites greatly hinders the practical applications of LMBs in portable electronics and electric vehicles. Constructing stable and efficient solid electrolyte interphase (SEI) is among the most effective strategies to inhibit the dendrite gro...
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We report direct visualization of electrochemical lithiation and delithiation of Au anodes in a commercial LiPF6/EC/DEC electrolyte for lithium ion batteries using transmission electron microscopy (TEM). The inhomogeneous lithiation, lithium metal dendritic growth, electrolyte decomposition, and solid-electrolyte interface (SEI) formation are observed in situ. These results shed lights on strat...
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The reaction between an uncharged Li2FeSiO4 (LFS) cathode and a LiPF6-EC/DMC electrolyte is revealed by in situ XANES in coin cells. This study shows clear evidence of delithiation and iron oxidation in LFS prior to cycling. Subsequent cycling appears to partially restore the original lithiation level, an observation that needs to be taken into consideration in future LFS development work.
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Aiming at an improved knowledge of the formation of the solid electrolyte interphase (SEI), as basis for the safe and efficient use of new anode materials, we investigated the SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. While the EIS measurements performed at equidista...
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It is well known that when propylene carbonate (PC) is used as the primary solvent with common inorganic salts like LiPF6 there is essentially continuous electrolyte reduction with a graphite electrode at ca. 0.9 V vs. Li/Li, accompanied by gassing and graphite exfoliation. However, co-intercalation and subsequent reduction occurs only with PC and not the chemically closely related solvent ethy...
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ژورنال
عنوان ژورنال: Journal of Energy Chemistry
سال: 2020
ISSN: 2095-4956
DOI: 10.1016/j.jechem.2019.05.017